Here's my attempt at a list of 'official' tier 4 modules, either released with the ampersand (official D&D content released by wotc), or without the ampersand but still by WotC's Adventurers League team (not necessarily the same 'officialdom' as content released with the ampersand). The list is a work in progress.
Hardcover Books
- Waterdeep: Dungeon of the Mad Mage
- Tales of the Yawning Portal (Tomb of Horrors)
Adventure League
- Season 3, Rage of Demons
- DDAL00-02, Lost Tales of Lost Myth Drannor
- Season 5, Storm King's Thunder:
- DDAL05-18, The Mysterious Isle
- DDAL05-19, The Eye of Xxiphu
- Season 6, Tales From the Yawning Portal
- DDAL06-03, Crypt of the Death Giants
- DDEP06-03, Hecatomb
- Season 7, Tomb of Annihilation
- DDAL07-15, Streams of Crimson
- DDAL07-16, Pools of Cerulean
- DDAL07-17, Cauldron of Sapphire
- DDAL07-18, Turn Back the Endless Night
- DDEP07-02, Drums of the Dead
- Season 8, Waterdeep
- DDAL08-16, A Change of Address
- DDAL08-17, The Tower of Ahghairon
- DDAL08-18, Moving Day
- DDEP08-03, Last Call at the Yawning Portal
- Season 9, Baldur's Gate: Descent into Avernus
- DDAL09-19, Fang and Claw
- DDAL09-20, Where Devils Fear to Tread
- Dreams of the Red Wizard
- DRW-08, The Harrowing Hell
- DRW-19, Fall the Cold Night
- DRW-20, The Death of Szass Tam
- DRWEP-02, Wings of Death
- DRWEP-04, Tears Among the Stars
- Adventure League Season 00
- DDAL00-02, The Lost Tales of Myth Drannor
- DDAL00-03, Those that Came Before
- DDAL00-10, Trust and Understanding
- DDAL00-11, Pipyap's Guide to All the Nine Hells
- DDAL00-12, Infernal Encounters
- DDEP00-01, The Red War
- Eberron
- DDALEB-17, The Final Tribute
- DDALEB-18, Scales of War
- DDALEB-19, Back to the Mud
- DDALEB-20, Old Scores
- DDALEB-EP04, The Last War